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| Baconnais, Isabelle; Rouxel, Olivier; Dulaquais, Gabriel; Boye, Marie. |
| A new technique for the determination of dissolved copper isotope composition (δ65Cu) of seawater was applied to examine copper sources and internal cycling in the Mediterranean Sea. A succession of chelating resin with nitrilotriacetic acid functional groups and strong base anion exchange resin, together with optimization of the multi-collector inductively coupled plasma mass spectrometry set-up allowed to isolate copper from seawater matrix and to measure the 65Cu/63Cu ratios in seawater with an external precision of 0.06‰ (2 s.d.). This method was first applied for inter-comparison measurements to surface and deep waters sampled at station BATS in the North Atlantic Ocean. Disparities in δ65Cu reported here and in the literature over these samples... |
| Tipo: Text |
Palavras-chave: Copper isotope; Seawater; Mediterranean Sea; Geotraces; Isotope fractionation. |
| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00457/56880/58742.pdf |
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| Baronas, J. Jotautas; Hammond, Douglas E.; Bennett, Mia M.; Rouxel, Olivier; Pitcher, Lincoln H.; Smith, Laurence C.. |
| Glacial environments offer the opportunity to study the incipient stages of chemical weathering due to the high availability of finely ground sediments, low water temperatures, and typically short rock-water interaction times. In this study we focused on the geochemical behavior of germanium (Ge) in west Greenland, both during subglacial weathering by investigating glacier-fed streams, as well as during a batch reactor experiment by allowing water-sediment interaction for up to 2 years in the laboratory. Sampled in late August 2014, glacial stream Ge and Si concentrations were low, ranging between 12–55 pmol/L and 7–33 µmol/L, respectively (Ge/Si = 0.9–2.2 µmol/mol, similar to parent rock). As reported previously, the dissolved stable Ge isotope ratio... |
| Tipo: Text |
Palavras-chave: Glacial weathering; Germanium; Isotope fractionation; Amorphous silica; Experimental dissolution. |
| Ano: 2021 |
URL: https://archimer.ifremer.fr/doc/00684/79577/82249.pdf |
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| Lotfi-kalahroodi, Elaheh; Pierson-wickmann, Anne-catherine; Guénet, Hélène; Rouxel, Olivier; Ponzevera, Emmanuel; Bouhnik-lecoz, Martine; Vantelon, Delphine; Dia, Aliou; Davranche, Mélanie. |
| Colloids have been recognized as key vectors of pollutants in aqueous environment. Amongst them, those formed by iron (Fe) and organic matter (OM) are of major importance due to their ubiquity in the surface environment and strong affinity for metals. In the recent years, Fe stable isotopes have been increasingly used to elucidate the sources and biogeochemical cycling of Fe in Earth's surface environments. In this study, we aim to elucidate (i) the possible Fe isotopic signature resulting from the Fe/OM colloid formation and (ii) the mechanisms involved in the development of such isotopic signature. For this purpose, Fe-OM associations were synthesized through binding and titration experiments. Various pH levels were used in order to study the isotope... |
| Tipo: Text |
Palavras-chave: Filtration; Size fractionation; Isotope fractionation; Colloidal; Dissolved; Fe isotopes. |
| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00480/59174/61811.pdf |
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| Fujii, Toshiyuki; Moynier, Frederic; Agranier, Arnaud; Ponzevera, Emmanuel; Abe, Minori; Uehara, Akihiro; Yamana, Hajimu. |
| Environmental transport of Tl is affected by redox reaction between Tl(I) and Tl(III) and ligand exchange reactions of them. In order to deepen the knowledge of Tl chemistry, we investigated fractionation of Tl stable isotopes (Tl-203 and Tl-205) in a chemical exchange system. Tl isotopes were fractionated in a liquid-liquid extraction system, in which aqueous and organic phases are hydrochloric acid solution and dichloroethane including a crown ether, respectively. After purification by ion-exchange chemistry, the isotope ratio of Tl-205/Tl-203 in equilibrated aqueous phase was measured precisely by multiple-collector-inductively-coupled-plasma-mass-spectrometry. A large isotope fractionation > 1 aEuro degrees was found. Electronic structures of... |
| Tipo: Text |
Palavras-chave: Thallium; Isotope fractionation; Redox; Ligand exchange; Nuclear field shift; Ab initio calculation. |
| Ano: 2013 |
URL: http://archimer.ifremer.fr/doc/00135/24624/22691.pdf |
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| Brugier, Yann-aurélien; Barrat, Jean-alix; Gueguen, Bleuenn; Agranier, Arnaud; Yamaguchi, Akira; Bischoff, Addi. |
| The Ureilite Parent Body (UPB) was a C-rich planetary embryo disrupted by impact. Ureilites are fragments of the UPB mantle and among the most numerous achondrites. Zinc isotopic data are presented for 26 unbrecciated ureilites and a trachyandesite (ALM-A) from the same parent body. The δ66Zn values of ureilites range from 0.40 to 2.71 ‰ including literature results. Zinc isotopic compositions do not correlate with the compositions of olivine cores, with C and O isotopic compositions, with Zn abundances, nor with shock grades. The wide range of δ66Zn displayed by the ureilites is chiefly explained by evaporation processes that took place during the catastrophic breakup of the UPB. During breakup, the high temperatures of the UPB mantle allowed Zn to... |
| Tipo: Text |
Palavras-chave: Ureilite; Zinc isotopic composition; Isotope fractionation; Shock. |
| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00472/58335/60889.pdf |
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